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Out of curosity have you tried unlinking one of the accounts, and then trying...I know it should work the right way with both accounts but this might help narrow down the problem, you might also try calling VZW maybe tech support has a decent answer
Don't forget: now you should have each account showing up on this screen, under "Manage Accounts." You need to check two things. First, does the green sync icon appear next to each of your accounts? Second, select each account from this screen, and make sure each "data type" (contacts, Gmail, Calendar, etc.) is turned on.
It's pretty easy to have one data type turned on (e.g., contacts) while others are turned off (I'm not sure what the default behavior is when you add your second account). From the "Accounts and Sync" screen, though, it will only tell you that sync is on for that account, but not which data type.