Will I be able to connect to my pc in sleep mode? Then authenticate as a user on that workstation?
if your computer is in sleep mode it will need physical prompt, like pushing the power button, to 'wake up'. no remote access program will do that for you.
if you leave your computer powered up, but lock the desktop which requires authentication to unlock it, then phonemypc will not work in it's current version. in this case you're better off with one of the rdp apps that can connect to your computer and allow you to log in using windows credentials.
You can wake up a sleeping computer with WOL (wake on lan). You just need to set up your computer properly to wake from magic packets.
A quick search on the market showed some WOL apps.
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