Would it be possible for someone to post the guides from the dev kit in .png format? I don't use photoshop and I can't find anything else that will open the files, thanks....
No need. When you download a skin they go in your "data"-> "beautifulwidgets"-> "skins" / "tskins" / "wskins" folders. Those files are already in .png format and you can use those. Just create your own with the same dimensions and save them right over the originals.
When you make your own skins, do they need to be compiled like normal .9 images?
No, the only Beautiful Widgets skins that require .9 images are for the new Super Clock. All of the others (home, weather, toggle) use standard .png's.
Hope this helps!