Go to app Drawer, Then Device Setup, Connect Accounts, Corporate Sync
Email Address (The email address of the account your wanting to sync)
Password (To the Account)
Domain (Doesn't need filled out)
Username (Normally the First part of your corporate Email with the @blank)
Ok on mine once I filled all of that in and Clicked next I got an error that backed me out to the same screen but added a URL line and a Check box for certificate. In the URL use the OWA address for your corporate email but do not put
www.email.JoeBlow.com it will not accept it and will give you Error. It should look like this email.JoeBlow.com If you have this line for URL filled in correctly and you still get an Error.
Uncheck the Security Certificate box. Some times this will correct any issues.
To answer the second part of your Question yes mine sync all, Contacts, calendar and Emails. I had some Trouble getting mine to Talk the first go round but I kept playing with the Certificate Box and URL and it meshed up fine.
I hope this helps. Corporate Sync is a pain how ever necessary for some of us. I hope you sort it out but I can assure you, your issue has nothing to do with this ROM